State-resolved reactivity of CH4 on Pt(110)-(1×2): The role of surface orientation and impact site

The reactivity of methane (CH(4)) on Pt(110)-(1 x 2) has been studied by quantum state-resolved surface reactivity measurements. Ground state reaction probabilities, S(0)(v=0) congruent with S(0)(laser-off), as well as state-resolved reaction probabilities S(0)(2nu(3)), for CH(4) excited to the first overtone of the antisymmetric C-H stretch (2nu(3)) have been measured at incident translational energies in the range of 4-64 kJ/mol. We observe S(0)(2nu(3)) to be up to three orders of magnitude higher than S(0)(v=0), demonstrating significant vibrational activation of CH(4) dissociation on Pt(110)-(1 x 2) by 2nu(3) excitation. Furthermore, we explored the azimuthal and polar incident angle dependence of S(0)(2nu(3)) and S(0)(v=0) for a fixed incident translational energy E(t)=32 kJ/mol. For incidence perpendicular to the missing row direction on Pt(110)-(1 x 2) and polar angles theta>40 degrees, shadowing effects prevent the incident CH(4) molecules from impinging into the trough sites. Comparison of this polar angle dependence with reactivity data for incidence parallel to the missing rows yields state-resolved site specific reactivity information consistent with a Pt(110)-(1 x 2) reactivity that is dominated by top layer Pt atoms located at the ridge sites. A comparison of S(0)(v=0) measured on Pt(110)-(1 x 2) and Pt(111) yields a lower average barrier for Pt(110)-(1 x 2) by 13.7+/-2.0 kJ/mol.