Ionic Liquid‐Nanoparticle Hybrid Electrolytes and their Application in Secondary Lithium‐Metal Batteries

材料科学 电解质 纳米颗粒 离子液体 锂(药物) 阳极 金属锂 金属 化学工程 枝晶(数学) 离子键合 无机化学 离子电导率 纳米技术 离子 电极 冶金 有机化学 催化作用 化学 医学 物理化学 内分泌学 工程类 几何学 数学
作者
Yingying Lü,Shyamal Das,Surya S. Moganty,Lynden A. Archer
出处
期刊:Advanced Materials [Wiley]
卷期号:24 (32): 4430-4435 被引量:297
标识
DOI:10.1002/adma.201201953
摘要

Advanced MaterialsVolume 24, Issue 32 p. 4430-4435 Communication Ionic Liquid-Nanoparticle Hybrid Electrolytes and their Application in Secondary Lithium-Metal Batteries Yingying Lu, Yingying Lu School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorShyamal K. Das, Shyamal K. Das School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorSurya S. Moganty, Surya S. Moganty School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorLynden A. Archer, Corresponding Author Lynden A. Archer [email protected] School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201.Search for more papers by this author Yingying Lu, Yingying Lu School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorShyamal K. Das, Shyamal K. Das School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorSurya S. Moganty, Surya S. Moganty School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201Search for more papers by this authorLynden A. Archer, Corresponding Author Lynden A. Archer [email protected] School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853-5201.Search for more papers by this author First published: 12 July 2012 https://doi.org/10.1002/adma.201201953Citations: 266Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ionic liquid-tethered nanoparticle hybrid electrolytes comprised of silica nanoparticles densely grafted with imidazolium-based ionic liquid chains are shown to retard lithium dendrite growth in rechargeable batteries with metallic lithium anodes. The electrolytes are demonstrated in full cell studies using both high-energy Li/MoS2 and high-power Li/TiO2 secondary batteries. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_201201953_sm_suppl.pdf185 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 P. G. Bruce, B. Scrosati, J.-M. Tarascon, Angew. Chem. Int. Ed. 2008, 47, 2930. 2 A. S. Arico, P. Bruce, B. Scrosati, J.-M. Tarascon, W. V. Schalkwijk, Nat. Mater. 2005, 4, 366. 3 B. Bunn, H. Kamath, J.-M. Tarascon, Science 2011, 334, 928. 4 G. Girishkumar, B. McCloskey, A. C. Luntz, S. Swanson, W. Wilcke, J. Phys. Chem. Lett. 2010, 1, 2193. 5 P. G. Bruce, S. A. Freunberger, L. J. Hardwick, J.-M. Tarascon, Nat. Mater. 2012, 11, 19. 6 N. Jayaprakash, J. Shen, S. S. Moganty, A. Corona, L. A. Archer, Angew. Chem. Int, Ed. 2011, 26, 5904. 7 J. Guo, T. Xu, C. Wang, Nano Lett. 2011, 11, 4288. 8 J.-M. Tarascon, M. Armand, Nature 2001, 414, 359. 9 J. K. Stark, Y. Ding, P. A. Kohl, J. Electrochem. Soc. 2011, 158, A1100. 10 J. A. Vega, J. Zhou, P. A. Kohl, J. Electrochem. Soc. 2009, 156, A253. 11 L. Gireaud, S. Grugeon, S. Laruelle, B. Yrieix, J. M. Tarascon, Electrochem. 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Mater. 2010, 22, 3677. 21 J. C. Maxwell, Treatise on Electricity and Magnetism, Oxford University Press, London, UK 1873. 22 J. L. Schaefer, S. S. Moganty, D. A. Yanga, L. A. Archer, J. Mater. Chem. 2011, 21, 10094. 23 S. S. Moganty, S. Srivastava, Y. Lu, J. L. Schaefer, L. A. Archer, Chem. Mater. 2012, 24, 1386. 24 M. Rosso, T. Gobron, C. Brissot, J.-N. Chazalviel, S. Lascaud, J. Power Sources 2001, 97–98, 804. 25 M. Rosso, C. Brissot, A. Teysso, M. Dolle, L. Sannier, J.-M. Tarascon, R. Bouchet, S. Lascaud, Electrochim. Acta. 2006, 51, 5334. 26 S. K. Das, R. Mallavajula, N. Jayaprakash, L. A. Archer, J. Mater. Chem. 2012, 22, 12988. 27 J. S. Chen, Y. L. Tan, C. M. Li, Y. L. Cheah, D. Luan, S. Madhavi, F. Y. C. Boey, L. A. Archer, X. W. Lou, J. Am. Chem. Soc. 2010, 132, 6124. 28 G. Armstrong, A. R. Armstrong, J. Canales, P. G. Bruce, Electrochem. Solid-State Lett. 2006, 9, A139. 29 G. Armstrong, A. R. Armstrong, P. G. Bruce, P. Reale, B. Scrosati, Adv. Mater. 2006, 18, 2597. 30 S. K. 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