材料科学
接受者
聚合物
结晶度
电子迁移率
位阻效应
电子受体
载流子
化学物理
纳米技术
结晶学
光化学
光电子学
立体化学
化学
凝聚态物理
复合材料
物理
作者
Huanhuan Liang,Cheng Liu,Zesheng Zhang,Xuncheng Liu,Quanfeng Zhou,Guohui Zheng,X. G. Gong,Lan Xie,Chen Yang,Lianjie Zhang,Bo He,Junwu Chen,Yi Liu
标识
DOI:10.1002/adfm.202201903
摘要
Abstract The quinoid‐donor‐acceptor (Q‐D‐A) strategy has recently emerged as a promising approach for constructing high mobility semiconducting polymers. In order to fully explore the potential of this strategy in improving the charge transport and elucidating the structure‐property‐performance relationships in Q‐D‐A polymers, a series of new polymers with different electron acceptor units and backbone coplanarity have been synthesized and characterized. All of the resulting Q‐D‐A polymers exhibit much more planar backbone conformations in comparison to their donor‐acceptor (D‐A) counterparts. Moreover, organic field‐effect transistors based on Q‐D‐A polymers exhibit excellent effective hole mobilities in a range of 0.44 to 3.35 cm 2 V −1 s −1 , most of which are orders of magnitude higher than those of their corresponding D‐A polymers. Notably, the hole mobility of 3.35 cm 2 V −1 s −1 is among the highest for the quinoidal‐aromatic polymers characterized by conventional spin‐coating methods. Furthermore, the role of electron acceptors in Q‐D‐A polymers has been comprehensively investigated. Polymers with stronger acceptor units are more inclined to deliver edge‐on lamellas, high film crystallinity, small effective hole masses, and decent operational stability. The detailed structure‐property‐device performance relationship will pave the way toward high performance semiconducting polymers using the potent Q‐D‐A strategy.
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