Removal of organochlorine pesticides (OCPs) from aqueous solutions using hydrogen peroxide, ultrasonic waves, and a hybrid process

过氧化氢 氧化剂 化学 水溶液 杀虫剂 环境化学 分解 超声波传感器 超声 污染物 色谱法 有机化学 农学 声学 生物 物理
作者
Małgorzata Kida,Sabina Ziembowicz,Piotr Koszelnik
出处
期刊:Separation and Purification Technology [Elsevier]
卷期号:192: 457-464 被引量:47
标识
DOI:10.1016/j.seppur.2017.10.046
摘要

The work detailed here investigated the efficiency of oxidizing technologies in clearing aqueous solutions of organochlorine pesticides (OCPs), which are known endocrine-disrupting compounds (EDCs), and an important group of environmental pollutants. The three processes considered entailed oxidation by hydrogen peroxide or ultrasonic waves, as well as a combined H2O2/sonication process, with the impacts of time, pH, pesticide concentration and hydrogen peroxide concentration on TOC (total organic carbon) and pesticide removal all tested. Results confirmed the greater effectiveness of TOC decomposition when ultrasonic waves were assisted by hydrogen peroxide, as opposed to when the process involved hydrogen peroxide (only after 60 min). At the beginning of oxidation, the hybrid process was less effective than that using ultrasonic waves alone. A reaction time has a significant impact on the results. Furthermore, as TOC results failed to offer an accurate reflection of the removal of individual substances from reaction mixture, chromatographic analysis was also carried out following the selected processes. An attempt to identify and characterize the degradation products of the tested pesticides was also made, and most pesticides were found to have been degraded completely. Chromatograms do not suggest any formation of by-products during the oxidation process.
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