化学
铪
锆
硝酸
萃取(化学)
化学计量学
水溶液
傅里叶变换红外光谱
分析化学(期刊)
核化学
无机化学
色谱法
物理化学
量子力学
物理
作者
Hongyang He,Fei Xu,Qiaolei Li,Panfei Dong,Jian Zheng,Chenjie Wu,Zhengyan He,Jun Qu,Zhigao Xu,Ruan Chi,Ming Wu
出处
期刊:Hydrometallurgy
[Elsevier]
日期:2021-06-01
卷期号:202: 105600-105600
被引量:15
标识
DOI:10.1016/j.hydromet.2021.105600
摘要
Extraction and separation of hafnium (Hf) from zirconium (Zr) in HNO3 solution were carried out with Cyanex572 as extractant. Hf could be selectively extracted with an optimized extraction rate of 76.8%, and the separation factor between Hf and Zr could reach up to 15.7 when the concentration of Zr(IV), Hf(IV), H+, NO3− and (NH4)2SO4 in aqueous phase were fixed at 110 g/L, 3.0 g/L, 2.6 M, 1.8 M and 0.8 M, respectively. The stoichiometry and coordination structure of the extracted complex for Hf was investigated by slope analysis, Fourier transform infrared (FT-IR) spectrometry and nuclear magnetic resonance (NMR) spectrometry. It was found that HfO2+ in nitric acid medium could be extracted into the organic phase through two routes. The dominant route was via a cation-exchange mechanism, according to 2HfO2+aq + H2A2 org + 2NO3̄ aq↔ (HfO2+)2·(NO3̄)2·A2 org + 2H+aq. Meanwhile, the subordinate route was coordinate with PO in Cyanex572 extractant. Therefore, it is possible to developing an effective solvent extraction system to separate Hf from Zr by utilizing Cyanex572.
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