量子点
机制(生物学)
光催化
异质结
还原(数学)
材料科学
光电子学
纳米技术
化学
物理
量子力学
催化作用
几何学
数学
生物化学
作者
Junzhi Yan,Yuming Sun,Jinfa Cai,Ming Cai,Bo Hu,Yan Yan,Qian Zhang,Xu Tang
出处
期刊:Catalysts
[MDPI AG]
日期:2024-09-06
卷期号:14 (9): 599-599
标识
DOI:10.3390/catal14090599
摘要
It is important to improve the separation ability of photogenerated electrons and the adsorption capacity of carbon dioxide (CO2) for efficient photoreduction of CO2. Here, we synthesized ZnCdS quantum dots (ZCS-QDs) and cerium dioxide nanosheets (CeO2) using the solvothermal method and calcination method. We combined CeO2 and ZCS-QDs to effectively enhance the charge separation efficiency, and the lifetime of photogenerated electrons was increased 4.5 times. The CO evolution rate of the optimized composite (ZCS-QDs/CeO2) was up to 495.8 μmol g−1 h−1, and it had 100% product selectivity. In addition, the stability remained high after five cycles. The CO2 adsorption capacity of the catalyst surface was observed by in situ FTIR. The test results showed that improving CO2 capture ability and promoting photogenic electron separation had positive effects on enhancing photoreduction of CO2. This study provides a reference for constructing a zero-dimensional–two-dimensional (0D–2D) heterojunction and explores potential CO2 reduction reaction mechanisms.
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