微观结构
材料科学
压电
陶瓷
铁电性
复合材料
铁电陶瓷
矿物学
光电子学
电介质
化学
作者
Fenghong Shao,Chen Chen,Xiang He,Lu Wang,Muzaffar Ahmad Boda,Zhiguo Yi
摘要
Abstract Sr 2 Nb 2 O 7 (SNO) ceramics are promising high‐temperature piezoelectric materials due to their high Curie temperature ( T C ), good thermal stability, and high electrical resistivity. However, SNO presents low piezoelectric activity ( d 33 < 1 pC/N). Here, we successfully obtain textured SNO ceramics with an orientation factor of 0.86 by microstructure regulation. Saturated polarization‐electric loop was obtained in textured ceramic with remanent polarization P r ∼3.56 µC/cm 2 and coercive field E C ∼53.4 kV/cm. The piezoelectric coefficient d 33 of the textured SNO ceramics is increased to 3.2 pC/N, with a high T C of 1342°C, while the low‐textured SNO ceramics exhibit no effective d 33 . Meanwhile, the piezoelectric coefficient d 33 of textured SNO ceramics maintains consistency even at 1300°C, showing excellent thermal stability. The underlying mechanism driving this improvement is elucidated, emphasizing the facilitated domain‐wall motion enabled by the engineered microstructure. Furthermore, textured SNO ceramics exhibit high resistivity of 1.33 × 10 6 Ω⋅cm at 800°C. This study presents a simple and feasible microstructure engineering approach to enhance the piezoelectric properties of layer‐structured materials, offering valuable insights into the design and development of ceramics for diverse applications.
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