A Review on Architecting Rationally Designed Metal‐Organic Frameworks for the Next‐Generation Li‐S Batteries

Abstract The modern era demands the development of energy storage devices with high energy density and power density. There is no doubt that lithium‒sulfur batteries (Li‒S) claim high theoretical energy density and have attracted great attention from researchers, but fundamental exploration and practical applications cannot converge to utilize their maximum potential. The design parameters of Li‐S batteries involve various complex mechanisms, and their obliviousness has resulted in failure at the commercial level. This article presents a review on rationally designed metal–organic frameworks (MOFs) for improving next‐generation Li‐S batteries. The use of MOFs in Li‐S batteries is of great interest because of their large surface area, porous structure, and selective permeability for ions. The working principles of Li‐S batteries, the commercialization of Li‐S batteries, and the use of MOFs as electrodes, electrolytes, and separators are critically examined. Finally, designed strategies (host structure, binder improvement, separator modification, lithium metal protection, and electrolyte optimization) are developed to increase the performance of Li‐S batteries.