面(心理学)
过电位
催化作用
电催化剂
材料科学
Crystal(编程语言)
化学工程
电解质
聚乙烯吡咯烷酮
纳米技术
化学
物理化学
电极
高分子化学
电化学
有机化学
计算机科学
五大性格特征
工程类
社会心理学
人格
程序设计语言
心理学
作者
Lei Huang,Xiongchao Lin,Jun Zhang,Zhe Sheng,Qian Wang,Fan Zhang,Sijian Qu,Yonggang Wang
标识
DOI:10.1016/j.apcata.2022.118803
摘要
Crystal facet engineering is considered to be a powerful method to maximize the inherent catalytic properties of electrocatalysts. In this research, polyvinylpyrrolidone (PVP) served as a surfactant to realize the controllable synthesis of sub-microspheres NiCo2S4 with a highly exposed (400) crystal facet. The sub-microspheres NiCo2S4 (P-0.2) shows excellent catalytic activities as a cathode toward hydrogen evolution reaction (HER) with a lower overpotential of 235 mV at 10 mA·cm−2 in alkaline electrolyte. Moreover, the sub-microspheres NiCo2S4 presents satisfactory durability in the alkaline solution for 24 h. Such remarkable HER performance of electrocatalyst is benefited from the unique sub-microspheres structure, which could highly expose specific crystal facets to provide abundant active sites, and thus enhance the mass/electron transfer efficiency. Furthermore, the increased exposure of (400) facet of NiCo2S4 crystal will offer more S2- during HER, it can effectively stabilize the reaction intermediates.
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