3D Pathways Enabling Highly‐Efficient Lithium Reservoir for Fast‐Charging Batteries

Abstract Enhancing the mobility of lithium‐ions (Li + ) through surface engineering is one of major challenges facing fast‐charging lithium‐ion batteries (LIBs). In case of demanding charging conditions, the use of a conventional artificial graphite (AG) anode leads to an increase in operating temperature and the formation of lithium dendrites on the anode surface. In this study, a biphasic zeolitic imidazolate framework (ZIF)‐AG anode, designed strategically and coated with a mesoporous material, is verified to improve the pathways of Li + and electrons under a high charging current density. In particular, the graphite surface is treated with a coating of a ZIF‐8‐derived carbon nanoparticles, which addresses sufficient surface porosity, enabling this material to serve as an electrolyte reservoir and facilitate Li + intercalation. Moreover, the augmentation in specific surface area proves advantageous in reducing the overpotential for interfacial charge transfer reactions. In practical terms, employing a full‐cell with the biphasic ZIF‐AG anode results in a shorter charging time and improved cycling performance, demonstrating no evidence of Li plating during 300 cycles under 3.0 C‐charging and 1.0 C‐discharging. The research endeavors to contribute to the progress of anode materials by enhancing their charging capability, aligning with the increasing requirements of the electric vehicle applications.