卡宾
盐(化学)
催化作用
基础(拓扑)
化学
组合化学
反应条件
有机化学
高分子化学
数学
数学分析
作者
Somnath Bauri,Arya Ramachandran,Arnab Rit
标识
DOI:10.1002/asia.202201301
摘要
An unprecedented base-catalyzed hydroarylation of isocyanates with azolium salts was developed, which follows a simple reaction pathway and provided facile access to diverse C2-amidated azolium salts under mild conditions. Importantly, this methodology can also be applied for the successive C2-amidation of a bisimidazolium salt with two different isocyanates to provide the corresponding unsymmetrically substituted bisamide derivatives. Notably, the obtained amidated salts can also serve as a prominent carbene surrogate for the synthesis of metal-NHC complexes.
科研通智能强力驱动
Strongly Powered by AbleSci AI