Three-dimensional structured electrode for electrocatalytic organic wastewater purification: Design, mechanism and role

Considering the growing need in decentralized water treatment, the application of electrocatalytic processes (EP) to achieve organic wastewater purification will be dominant in the near future due to high efficiency, small reactor assembly as well as the flexibility of operation and management. The catalytic performance of electrode materials determines the development of this technology. Among them, the unique three-dimensional (3D) structure electrode shows better performance than two-dimensional (2D) electrode in increasing mass transfer, enhancing adsorption and exposing more active sites. Hence, this review starts with the introduction of definition, classification, advantages and disadvantages of 3D electrode materials. Then a critical discussion on the design and construction of 3D electrode materials for organic wastewater purification application is provided. Next, the removal mechanism of organic pollutants on the surface of 3D electrode, the role of 3D structure, the design of reactor with 3D electrode, the conversion and toxicity of degradation products, electrode energy efficiency, stability and cost, are comprehensively reviewed. At last, current challenges and future perspectives for the development of 3D electrode materials are addressed. We deem that this review will provide a valuable insight into the design and application of 3D electrodes in environmental water purification.