Key to High Performance Ion Hybrid Capacitor: Weakly Solvated Zinc Cations

Abstract Zinc ion hybrid capacitors suffer from lack of reversibility and dendrite formation. An electrolyte, based on a solution of a zinc salt in acetonitrile and tetramethylene sulfone, allows smooth zinc deposition with high coulombic efficiency in a Zn||stainless steel cell (99.6% for 2880 cycles at 1.0 mA cm −2 , 1.0 mAh cm −2 ). A Zn||Zn cell operates stably for at least 7940 h at 1.0 mA cm −2 with an area capacity of 10 mAh cm −2 , or 648 h at 90% depth of discharge and 1 mA cm −2 , 9.0 mAh cm −2 . Molecular dynamics simulations reveal the reason for the excellent reversibility: The zinc cation is only weakly solvated than in pure tetramethylene sulfone with the closest atoms at 3.3 to 3.8 Å. With this electrolyte, a zinc||activated‐carbon hybrid capacitor exhibits an operating voltage of 2.0 to 2.5 V, an energy‐density of 135 Wh kg −1 and a power‐density of 613 W kg −1 at 0.5 A g −1 . At the very high current‐density of 15 A g −1 , 29.3 Wh kg −1 and 14 250 W kg −1 are achieved with 81.2% capacity retention over 9000 cycles.