Hierarchical Porous Amidoximated Metal–Organic Framework for Highly Efficient Uranium Extraction

SmallEarly View 2306545 Research Article Hierarchical Porous Amidoximated Metal–Organic Framework for Highly Efficient Uranium Extraction Jin Li, Jin Li Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorKai Tuo, Kai Tuo Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorCongbin Fan, Congbin Fan Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorGang Liu, Gang Liu Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorShouzhi Pu, Corresponding Author Shouzhi Pu [email protected] YuZhang Normal University, Nanchang, 330013 P. R. China E-mail: [email protected]; [email protected]Search for more papers by this authorZhijian Li, Corresponding Author Zhijian Li [email protected] orcid.org/0000-0002-3837-7001 Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. China E-mail: [email protected]; [email protected]Search for more papers by this author Jin Li, Jin Li Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorKai Tuo, Kai Tuo Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorCongbin Fan, Congbin Fan Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorGang Liu, Gang Liu Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. ChinaSearch for more papers by this authorShouzhi Pu, Corresponding Author Shouzhi Pu [email protected] YuZhang Normal University, Nanchang, 330013 P. R. China E-mail: [email protected]; [email protected]Search for more papers by this authorZhijian Li, Corresponding Author Zhijian Li [email protected] orcid.org/0000-0002-3837-7001 Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013 P. R. China E-mail: [email protected]; [email protected]Search for more papers by this author First published: 16 November 2023 https://doi.org/10.1002/smll.202306545Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract With the rapid development of industry and technology, high-efficiency extraction of uranium from seawater is a research hotspot from the aspect of nuclear energy development. Herein, a new amidoximated metal–organic framework (UiO-66-DAMN-AO) constructed through a novel organic ligand of 2-diaminomaleonitrile-terephthalic acid (BDC-DAMN) is designed via one-step post-synthetic methods (PSM), which possess the merit of abundant multiaffinity sites, large specific surface area, and unique porous structure for efficient uranium extraction. Adopting one-step PSM can alleviate the destruction of structural stability and the reduction of the conversion rate of amidoxime groups. Meanwhile, introducing the BDC-DAMN ligand with abundant multiaffinity sites endow UiO-66-DAMN-AO with excellent adsorption ability (Qm = 426.3 mg g−1) and selectivity. Interestingly, the UiO-66-DAMN-AO has both micropores and mesopores, which may be attributed to the partial etching of UiO-66-DAMN-AO during the amidoximation. The presence of mesopores improves the mass transfer rate of UiO-66-DAMN-AO and provides more exposed active sites, favoring the adsorption of uranium on UiO-66-DAMN-AO. Thus, this study provides a feasible strategy for modifying metal–organic framework (MOFs) with plentiful amidoxime groups and the promising prospect for MOF-based materials to adsorb uranium from ocean. Conflict of Interest The authors declare no conflict of interest. Open Research Data Availability Statement The data that support the findings of this study are available in the supplementary material of this article. Supporting Information Filename Description smll202306545-sup-0001-SuppMat.pdf2 MB Supporting Information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1R. Li, H. Wang, J. Yan, R. Fu, B. Wang, C. 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