电泳剂
亲核细胞
组合化学
化学
烯胺
可见光谱
机制(生物学)
光催化
光化学
纳米技术
有机化学
材料科学
催化作用
物理
光电子学
量子力学
作者
Yu Han,Liyun Zhou,Chengyu Wang,Shangti Feng,Rong Ma,Jie‐Ping Wan
标识
DOI:10.1016/j.cclet.2023.108977
摘要
Enaminones, which possesses both the nucleophilic enamine as well as electrophilic enone structures, are well known versatile building blocks in organic synthesis. Meanwhile, visible light-mediated reactions have emerged as useful synthetic strategy with enhanced sustainability. Around the last decade, various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds. In this review, we describe the recent advances in visible light-mediated chemical transformations of enaminones. Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader. Finally, a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented.
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