Cover Picture: Enantiopure [6]‐Azairidahelicene by Dynamic Kinetic Resolution of a Configurationally Labile [4]‐Helicene

Enantiopure irida[6]helicenes combining chirality at the metal center and at the helicenic fragment are obtained by dynamic kinetic resolution of configurationally labile [4]helicenic ligands. These compounds exhibit perfect mirrored electronic circular dichroism (ECD) and circularly polarized phosphorescence (CPP) signals, as described by Carlos M. Cruz, Fernando P. Cossío, Zoraida Freixa, and co-workers in their Communication (e202406663).