Palladium-catalyzed regiodivergent arylamination/aryloxygenation of allenamide
化学
钯
催化作用
组合化学
立体化学
有机化学
作者
Jijiao Zeng,Hui Wang,Ze‐Hua Sun,Xinjin Li,Fenggang Sun,Qing Liu,Lizhi Zhang,Li‐Ping Xu,Hui Liu
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2022-01-01卷期号：9 (21): 5969-5975被引量：3
标识
DOI：10.1039/d2qo01271e
摘要
In regiodivergent arylamination/aryloxygenation of allenamides, use of Cy 2 NMe caused 2,1-arylamination and the corresponding alkenes were formed with excellent Z configuration. Whereas, utilizing Ag 2 CO 3 caused 2,3-aryloxygenation via an unexpected CO 2 insertion from Ag 2 CO 3 .
爱静静
Singularity
HEIKU
Hayat
不配.
kento
云瑾
curtisness
zzzyyy
shinysparrow
浅尝离白
rosalieshi
徐叽钰
8R60d8
tuanheqi
pluto
乐乐乐乐乐乐
于芋菊
Henry
Loooong
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