Dimethylamine Bismuth Iodide: A Lead‐Free Perovskite Enabling Ultra‐Sensitive UVC Photodetection with Low Operating Voltage and High Detectivity

Ultraviolet (UV) photodetectors (PDs) are essential for various applications, but traditional materials face challenges in cost, fabrication, and performance. This study introduces dimethylamine bismuth iodide (DMABI) as a promising lead-free perovskite for UV PDs, particularly in the UVC region. DMABI demonstrates exceptional device parameters, including an ultralow dark current of 0.12 pA at 0.05 V, a high on/off ratio of 7.1 × 10