镍
材料科学
催化作用
共晶体系
蚀刻(微加工)
化学工程
深共晶溶剂
电化学
碳纤维
溶剂
纳米技术
无机化学
化学
冶金
电极
图层(电子)
合金
有机化学
复合材料
物理化学
复合数
工程类
作者
Danxia Xu,Yuechao Yang,Baolong Zhang,Zhaohui Yang,Shuzi Liu,Tiancheng Mu
出处
期刊:Chemsuschem
[Wiley]
日期:2022-08-25
卷期号:15 (20)
被引量:9
标识
DOI:10.1002/cssc.202200822
摘要
The development of catalysts with relatively high current densities at low potentials for the electrooxidation of 5-hydroxymethylfurfural (HMF) is still challenging. In this study, an in situ deep eutectic solvent (DES) etching phosphorization strategy is developed to prepare nickel phosphides encapsulated in P,O-codoped carbon nanosheets (Ni-P@POC). The DES serves not only as an etchant to extract Ni2+ from the nickel foam, but also as a phosphorus source to form nickel phosphides in situ uniformly embedded in the carbon films to produce a sheet structure. The electrooxidation performance is further greatly improved by implementing an electrochemical activation step to transform Ni-P@POC into NiOOH/Ni-P@POC (t-Ni-P@POC). t-Ni-P@POC exhibits a low onset potential of 1.20 V vs. RHE and a high current density of 200 mA cm-2 at 1.33 V vs. RHE for HMF electrooxidation, outperforming most reported catalysts. The as-developed DES etching phosphorization strategy offers a facile, flexible, and universal route for the design of high-performance catalysts with specific nanostructures.
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