Selenium‐Doped Black Phosphorus for High‐Responsivity 2D Photodetectors

Se-doped black phosphorus (BP) crystal, in centimeter scale, is synthesized by a scalable gas-phase growth method under mild conditions. The Se-doped BP exhibits high quality with excellent electrical properties. The Se dope induces over 20-fold enhancement of responsivity (R) for BP-based 2D photodetectors, resulting in a high R and external quantum efficiency of 15.33 A W-1 and 2993%, respectively.