材料科学
莲花效应
聚合物
制作
复合材料
微流控
纤维
基质(水族馆)
纳米技术
接触角
纳米颗粒
纳米-
超细纤维
病理
有机化学
化学
地质学
替代医学
原材料
海洋学
医学
作者
Shaozhe Lü,Yi Zhao,Xu Hu,Lin Yuan,Yangchuan Ke
标识
DOI:10.1016/j.matlet.2019.127152
摘要
Inspired by the lotus leaf effect and strong adhesion ability of mussel adhesive protein in nature, highly efficient superhydrophobic polymer fiber fabrics were fabricated using a novel, facile and bottom-up assembly strategy that introduced SiO2/polydopamine/Ag nanoparticles/1H,1H,2H,2H-perfluorodecanethiol to three-dimensionally construct micro-nano hierarchical rough structures on the fabric surfaces with low surface energy. Results showed that the hierarchical substrate-core-shell-satellite architecture structure with three-tier distribution in the as-fabricated fabrics was successfully achieved. The obtained fabrics displayed water contact angles in the range from 147.8°±2.5° to 160.1°±2.8° with SiO2 particles of different sizes (0.2–0.4 μm). Moreover, the as-fabricated fabrics could effectively separate a variety of oil/water mixtures with high separation efficiencies beyond 90% and maintain good superhydrophobicity for 20 cycles. In addition, the mechanism for oil/water mixture separation was also discussed. Therefore, such superhydrophobic polymer fiber fabrics were promising in designing smart surfaces in, for example, oil/water separation, smart oil engineering (the conductivity of Ag nanoparticles on fabric surfaces), microfluidic devices, etc.
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