Towards Efficient Polymeric Binders for Transition Metal Oxides‐based Li‐ion Battery Cathodes

Abstract Transition metal oxide cathodes (TMOCs) such as LiNi 0.8 Mn 0.1 Co 0.1 O 2 and LiMn 1.5 Ni 0.5 O 4 have been widely employed in Li‐ion batteries (LIBs) owing to superior operating voltages, high reversible capacities and relatively low cost. Nevertheless, despite significant advancements in practical application, TMOC‐based LIBs face great challenges such as transition metal dissolution and volume expansion during cycling, which jeopardizes the future advance of high‐voltage TMOCs. As a critical component of cathode, polymeric binder acts as a crucial part in maintaining the mechanical and ion/electron conductive integrity between active particles, carbon additives, and the aluminum collector, hence minimizing cathode pulverization during battery cycling. Moreover, Polymeric binder with specialized functions is thought to offer a new solution to enhancing the electrochemical stability of the TMOCs. Therefore, this review aims at providing a comprehensive summary of the ideal requirements, design strategies and recent progress of polymeric binders for TMOCs. Future design perspectives and promising research technologies for advanced binders for high‐voltage TMOCs are introduced.