Wireless Electrochemical Gel Actuators

Abstract Soft actuators generate motion in response to external stimuli and are indispensable for soft robots, particularly future miniature robots with complex structure and motion. Similarly to conventional hard robots, electricity is suitable for the stimulation. However, previous electrochemical soft actuators require a tethered connection to a power supply, limiting their size, structure, and motion. Here, wireless electrochemical soft actuators composed of hydrogels and driven by bipolar electrochemistry are reported. Viologen, which dimerizes by one‐electron reduction and dissociates by one‐electron oxidation, is incorporated in the side chains of the gel networks and works as a reversible cross‐link. Wireless and reversible electrochemical actuation of the hydrogels, i.e., muscle‐like shrinking and swelling, is demonstrated at microscopic and even macroscopic scales.