材料科学
催化作用
分解水
调制(音乐)
纳米技术
化学工程
光催化
有机化学
美学
工程类
哲学
化学
作者
Hengyi Chen,Zehua Gao,Shijie Ren,Rui‐Ting Gao,Limin Wu,Lei Wang
标识
DOI:10.1002/aenm.202403067
摘要
Abstract The development of efficient and durable bifunctional electrocatalysts is essential for hydrogen production from acidic water splitting. Herein, a TiO 2 nanotube‐loaded Co‐doped Ru nanoparticle catalyst (RuCo/TiO 2 NTs) is reported that exhibits excellent activity and stability toward acidic oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The Ru─O─Ti bonding is enhanced by Co doping, and the metal carrier interaction between Ru nanoparticles and TiO 2 NTs is enhanced, which effectively stabilizes Ru species during OER and initiates hydrogen spillover accelerating HER kinetics. As a result, RuCo/TiO 2 NTs catalyst requires only 156 mV OER overpotential and 17 mV HER overpotential to achieve a current density of 10 mA cm −2 with a stability more than 500 h in acidic conditions. More importantly, benefiting from the excellent bifunctional activities, the proton exchange membrane electrolyte assembled from RuCo/TiO 2 NTs has excellent activity and robust stability (1000 h). This work opens a new avenue for the efficient energy conversion devices.
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