收缩率
材料科学
气凝胶
复合材料
抗压强度
质量分数
热塑性塑料
热导率
大气压力
杨氏模量
粒径
微观结构
模数
弹性模量
化学工程
海洋学
工程类
地质学
作者
Xiaofan Liu,Jilin Zheng,Zongyi Deng,Dalin He,Shuhai Huang,Huang Zhang,Mei Shi
标识
DOI:10.1080/00222348.2023.2240656
摘要
This article presents a rapid preparation method of phenolic aerogels using thermoplastic phenolic resin as a raw material under atmospheric pressure, a low temperature and mass fraction of the resin varying from 10 to 30%. The results showed that the initial stage of the aging time of the aerogel with resin mass fraction of 10% (PF-10) was at least 34 h to ensure no neck shrinkage during drying, while that with 30% phenolic content (PF-30) was only 1h. The prepared aerogels had a minimum density of 0.129 g/cm3 and a minimum shrinkage of 0.391%. With the increase of mass fraction of resin, the thermal conductivity of the aerogels decreased first and then increased, and PF-20 had the lowest thermal conductivity, being 0.037 W/(m·K). The effects of resin content on the microstructure were reflected in the pore size of aerogels which decreased from 773 nm for PF-10 to 43.328 nm for PF-30 and the particle size of the phenolic resin which decreased from 194 to 28 nm. The specific surface area increased from 37.707 to 177.231 m2/g, and the number of micropores increased. In terms of mechanical properties, the aerogel with 10% resin mass fraction had a minimum compressive strength of 0.342 MPa and a compressive modulus of 12.811 MPa, showing good elasticity. When the resin content was 30%, the strength and modulus increased to 8.309 and 348.060 MPa respectively. Its specific strength and specific modulus were 16.553 and 693.346 N·m/g, respectively, and the rigidity was greatly increased.
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