Bioinspired, Ultra‐Sensitive Flexible Strain Sensor Based on Ceramic Fiber Paper With Superhydrophobic and High‐Temperature‐Resistant Properties

Abstract Flexible strain sensors are indispensable components providing repeatable electronic signals responding to mechanical deformations. Nevertheless, there is a stringent demand for flexible sensors to maintain normal performance in daily use and even in harsh conditions, such as high humidity and high temperature. Herein, inspired by scorpions, a highly sensitive flexible strain sensor based on ceramic fiber paper (CFP) with superhydrophobic and high‐temperature‐resistant properties is developed by a combination of mechanical cutting and spray coating method, which minimizes performance degradation commonly seen in polymer‐based and textile‐based sensors under harsh conditions. The prepared strain sensor exhibits high sensitivity (gauge factor ≈1254), low detection limit (0.078%), fast response time (108 ms), and notable stability (over 10 000 cycles). The ultra‐high sensitivity originates from the existence of the micro‐scale cracks. To further improve stability of the device in some harsh conditions, superhydrophobic and heat‐resisting coatings consisting of SiO 2 aerogels and SiO 2 nanoparticles are introduced onto the surface of CFP. Owing to the synergistic effect of the high‐temperature resistance of ceramics fibers and the coatings, the device operates normally at temperature up to 220 °C with a water contact angle of 159°, showing great promises for harsh conditions, especially in the industrial and aerospace fields.