萃取(化学)
稀土
土(古典元素)
天体生物学
地质学
地球科学
化学
物理
色谱法
天文
作者
C.F. Carrozza,F. Dutoy,M.B. Stella
标识
DOI:10.17159/2411-9717/689/2024
摘要
Rare earth elements (REEs) are indispensable components in the manufacturing of high-tech devices, renewable energy technologies, and defence applications. As global demand for these elements continues to rise, there is a pressing need to optimize extraction processes for both efficiency and environmental sustainability. This study explores approaches to rare earth extraction using Ionquest® 801 and integrates a predictive modelling to enhance process understanding and optimization. We conducted a screening test varying pH process to evaluate the best extraction efficiency. Starting pregnant leach solution (PLS), solution was prepared in the lab with the following rare earth elements: La, Ce, Gd, Dy, and Υ, at 0.02 M for each element. The data obtained were used to develop empirical and mechanistic models to predict rare earth extraction yields and flowsheet. Further tests were performed by mixing specific concentrations of different extractant and/ or phase modifier. Our experimental results demonstrated the effectiveness of the proposed extraction methods, highlighting improvements in both yield and selectivity. The developed models successfully captured the complex relationships between process parameters and extraction efficiency, providing valuable insights for process optimization.
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