材料科学
电解质
离子
锂(药物)
电流密度
聚合物
离子运输机
原位
电流(流体)
聚合物电解质
化学工程
纳米技术
离子电导率
无机化学
电极
有机化学
物理化学
复合材料
化学
医学
物理
量子力学
工程类
电气工程
内分泌学
作者
Xunzhi Miao,Jianhe Hong,Shuo Huang,Can Huang,Yushi Liu,Min Liu,Quanquan Zhang,Hongyun Jin
标识
DOI:10.1002/adfm.202411751
摘要
Abstract In situ formed gel polymer electrolytes (GPEs) have advantages in safety and adaptability to current high‐voltage lithium‐ion batteries (LIBs). However, it is challenging for GPEs to achieve stable cycling at high current densities. A flexible framework is proposed for stable in situ GPE, by introducing ─CF 3 groups to the polymer network to establish rapid Li + transport channels, and incorporating secondary amine N─H groups to anchor anion. The obtained GPE exhibits a high ionic conductivity of 2.6 mS cm −1 and a high Li + transference number of 0.67. The assembled Li||NCM811 cell demonstrates excellent rate performance, with a discharging capacity of 112.3 mAh g⁻¹ at 10C, and capacity retention of 87.6% after 260 cycles at 1C. Furthermore, the assembled graphite||NCM811 cell demonstrates excellent long‐term cycling stability with impressive capacity retention of 73.2% after 300 cycles 3C (1.8 mA cm −2 ). This work presents a promising approach to enhancing the cycling stability of GPEs for high‐voltage LIBs at high current density.
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