光催化
氮化碳
分子内力
光化学
接受者
石墨氮化碳
电子受体
降级(电信)
载流子
材料科学
反应速率常数
化学
化学工程
催化作用
光电子学
有机化学
动力学
电信
量子力学
物理
工程类
计算机科学
凝聚态物理
作者
Chen Zhang,Zenglin Ouyang,Yang Yang,Long Xia,Lei Qin,Wenjun Wang,Yin Zhou,Deyu Qin,Fanzhi Qin,Cui Lai
标识
DOI:10.1016/j.cej.2022.137370
摘要
The inherent structural defects of graphitic carbon nitride (g-C3N4), especially low separation efficiency of photogenerated carriers, have greatly limits its photocatalytic degradation ability towards pollutants. Conjugated g-C3N4 (CN) with tailored donor–acceptor units have recently attracted great attention because of the controlled optical bandgap and favorable separation of charge carriers. Here, a novel 5-bromo-2-thiophenecarboxaldehyde (BTC) grafted CN photocatalyst (TCN) was prepared. The results have showed that this new material has significant performance advantages. Up to 2.43-fold apparent rate constant improvement in photocatalytic OTC degradation was realized using TCN-5 compared to CN, and the efficiency for OTC degradation was as high as 93%. And at the end of the reaction (at 60 min), the removal efficiency of TOC was 38%, which should be due to the accelerated the intramolecular charge separation and controllable electron migration. This work unravels intramolecular charge transfer in donor–acceptor structured CN for oxytetracycline photocatalytic degradation, which is expected to bring a promising approach for the photocatalytic degradation of antibiotics.
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