Sustainable strategy on microbial fuel cell to treat the wastewater for the production of green energy

Microbial fuel cell (MFC) is one of the promising alternative energy systems where the catalytic conversion of chemical energy into electrical energy takes places with the help of microorganisms. The basic configuration of MFC consists of three major components such as electrodes (anode and cathode), catalyst (microorganism) and proton transport/exchange membrane (PEM). MFC classified into four types based on the substrate utilized for the catalytic energy conversion process such as Liquid-phase MFC, Solid-phase MFC, Plant-MFC and Algae-MFC. The core performance of MFC is organic substrate oxidation and electron transfer. Microorganisms and electrodes are the key factors that decide the efficiency of MFC system for electricity generation. Microorganism catalysis degradation of organic matters and assist the electron transfer to anode surface, the conductivity of anode material decides the rate of electron transport to cathode through external circuit where electrons are reduced with hydrogen and form water with oxygen. Not limited to electricity generation, MFC also has diverse applications in different sectors including wastewater treatment, biofuel (biohydrogen) production and used as biosensor for detection of biological oxygen demand (BOD) of wastewater and different contaminants concentration in water. This review explains different types of MFC systems and their core performance towards energy conversion and waste management. Also provides an insight on different factors that significantly affect the MFC performance and different aspects of application of MFC systems in various sectors. The challenges of MFC system design, operations and implementation in pilot scale level and the direction for future research are also described in the present review.