立体专一性
催化作用
羟基化
化学
活动站点
组合化学
立体化学
有机化学
酶
作者
Laura Gómez,Isaac Garcia‐Bosch,Anna Company,Jordi Benet‐Buchholz,A. Polo,Xavier Sala,Xavi Ribas,Miguel Costas
标识
DOI:10.1002/anie.200901865
摘要
Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands.
科研通智能强力驱动
Strongly Powered by AbleSci AI