Investigation of reaction parameters, kinetics and mechanism of oleic acid esterification with methanol by using Amberlyst 46 as a catalyst

Abstract In this study, the effect of reaction parameters such as molar ratio of methanol to oleic acid, catalyst amount, reaction temperature and reaction time was investigated for esterification of oleic acid with methanol in the presence of Amberlyst 46. The conversion of 98.6% was obtained when the reaction was performed at 3:1 molar ratio of methanol to oleic acid, reaction temperature of 100 °C, catalyst amount of 15% and 2 h reaction time. The conversions with reused catalyst varied in the range of 96.8% to 98.3%. After the catalyst was reused for ten times under the same reaction conditions negligible catalytic activity loss (