热重分析
差示扫描量热法
锥形量热计
季戊四醇
阻燃剂
材料科学
热稳定性
傅里叶变换红外光谱
化学工程
相变材料
烧焦
量热法
热能储存
燃烧
化学
复合材料
有机化学
热的
气象学
工程类
物理
热力学
生物
生态学
作者
Renjie Chen,Xinyu Huang,Ruizhi Zheng,Delong Xie,Yi Mei,Ruqiang Zou
标识
DOI:10.1016/j.cej.2019.122500
摘要
Organic phase change materials are flammable, which limits their applications in heat storage and conversion. In the presented study, a phosphorus-grafted hexadecanol was blended with pentaerythritol phosphate (PEPA) to prepare flame-retardant phase change material (FRPCM). The thermal properties of FRPCM were evaluated by means of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and cone calorimetry. The flame-retardant mechanism was examined by thermogravimetric analysis-Fourier transform infrared spectrometry (TG-FTIR) and scanning electron microscopy (SEM) tests. The FRPCM maintains a promising heat storage capacity (186.9 J/g) and thermal stability after grafting and blending. The flame retardance analysis reveals that the grafted phosphorus group helps to promote char formation. PEPA extends the time before exposed combustible material ignites. The cone calorimeter test demonstrated that the peak heat release rate and total heat release are further decreased by more than 50%, owing to the synergistic effect between the phosphorus group and PEPA. The SEM results showed that a porous structure is formed during combustion. Self-extinguishment testing indicates that the FRPCM is extinguished in a much shorter time than is hexadecanol.
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