Adsorption mechanism of two pesticides on polyethylene and polypropylene microplastics: DFT calculations and particle size effects

呋喃丹 吸附 化学 氨基甲酸酯 弗伦德利希方程 杀虫剂 环境化学 有机化学 农学 生物
作者
Qiming Mo,Xingjian Yang,Jinjin Wang,Huijuan Xu,Wenyan Li,Qi Hua Fan,Shuang Gao,Wenyi Yang,Chengzhen Gao,Dehua Liao,Yongtao Li,Yulong Zhang
出处
期刊:Environmental Pollution [Elsevier]
卷期号:291: 118120-118120 被引量:96
标识
DOI:10.1016/j.envpol.2021.118120
摘要

Polyethylene (PE) and polypropylene (PP) microplastics (MPs), as carriers, can bind with pesticides, which propose harmful impacts to aqueous ecosystems. Meanwhile, carbofuran and carbendazim (CBD), two widely used carbamate pesticides, are toxic to humans because of the inhibition of acetylcholinesterase activity. The interaction between two MPs and two pesticides could start in farmland and be maintained during transportation to the ocean. Herein, the adsorption behavior and mechanism of carbofuran and carbendazim (CBD) by PE and PP MPs were investigated via characterization and density functional theory (DFT) simulation. The adsorption kinetic and thermodynamic data were best described by pseudo-second-order kinetics and the Freundlich models. The adsorption behaviors of individual carbofuran/CBD on both MPs were very similar. The CBD adsorption rate and capacity of PE and PP MPs were higher than those of carbofuran. This phenomenon explained the lower negative effects of DOM (oxalic acid, glycine (Gly)) on CBD adsorption relative to those of carbofuran. The presence of oxalic acid and Gly decreased the PE adsorption by 20.40-48.02% and the PP adsorption by 19.27-42.11%, respectively. It indicated the significance of DOM in carbofuran cycling. The adsorption capacities were negatively correlated with MPs size, indicating the importance of specific surficial area. Fourier transformation infrared spectroscopy before and after adsorption suggested that the adsorption process did not produce any new covalent bond. Instead, intermolecular van der Waals forces were one of the primary adsorption mechanisms of carbofuran and CBD by MPs, as evidenced by DFT calculations. Based on the zeta potential, the electrostatic interaction explained the higher adsorption CBD by MPs than carbofuran.
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