聚乙烯吡咯烷酮
材料科学
复合数
煅烧
镁
电池(电)
粒度
电化学
催化作用
阴极
微观结构
纳米
化学工程
肺表面活性物质
氨
核化学
冶金
复合材料
电极
化学
有机化学
生物化学
功率(物理)
物理
物理化学
量子力学
高分子化学
工程类
作者
Xiaohan Wu,Hui Liu,Jiaxi Zhang,Juemin Song,Jiefeng Huang,Wanli Xu,Yan Yang,Kun Yu
出处
期刊:Metals
[MDPI AG]
日期:2021-04-13
卷期号:11 (4): 633-633
摘要
La0.8Sr0.2MnO3 (LSM) catalyst is prepared via a sol-gel method and modified via a typical silver mirror reaction. Silver ammonia solution is reduced in a polyvinylpyrrolidone (PVP)-containing solution to obtain silver nanoparticles and sodium dodecyl sulfate (SDS) is added as a surfactant. The microstructure and morphology of the LSM-Ag composite powder are characterized. According to the results, the Ag particles precipitate on the LSM surface in elemental form and the grain size is about one hundred nanometers. The analysis of electrocatalytic performance of LSM-Ag cathodes with different amounts of silver loading reveals that the number of electrons transferred during the oxygen reduction reaction (ORR) of the cathode with an Ag content of 14% by weight reached 3.9, which is very close to that of commercial Pt/C catalysts. Similarly, the maximum power density of the air battery made of LSM-14%Ag is 73 mW/cm2, which exceeds that of 63 mW/cm2, found for the LSM battery. Finally, increasing the amount of silver loading allows one to improve the electrochemical performance of LSM catalysts. The best effect is achieved when the Ag loading exceeds 14%.
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