催化作用
铈
选择性催化还原
材料科学
钨
大气温度范围
结晶
无机化学
二氧化钛
硫黄
降水
核化学
化学
冶金
有机化学
气象学
物理
生物化学
作者
Zihao Fu,Guodong Zhang,Zhicheng Tang,Haitao Zhang
标识
DOI:10.1002/slct.202100598
摘要
Abstract A series of CeO 2 −WO 3 /TiO 2 catalysts were synthesized by the co‐precipitation method and used for selective catalytic reduction (SCR) of NO with NH 3 under medium‐low temperature conditions with metatitanic acid as Ti source. A more reasonable weight ratio of CeO 2 and WO 3 was explored. The catalytic activity enhanced with the increase of cerium content, but the catalytic activity changed slightly in the temperature range of 240 °C to 400 °C when the cerium content exceeded 15 %. Tungsten could enhance the sulfur resistance by adjusting the degree of crystallization, acidity in the SCR process. When the weight ratio of CeO 2 to WO 3 was 15: 8, the conversion rate of NO was more than 90 % in the temperature range of 240 °C to 440 °C. For 15 %CeO 2 ‐8 %WO 3 /TiO 2 catalyst, the NO conversion was maintained around 84 % when the mixed gas was introduced SO 2 . At the same time, we have optimized the selection of carriers, metatitanic acid as a carrier was better than titanium dioxide.
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