A Light(er) Approach for the Selective Hydrogenation of 5‐Hydroxymethylfurfural to 2,5‐Bis(hydroxymethyl)furan without External H2

The selective conversion of 5-hydroxymethyfurfural (HMF), a biomass-derived platform molecule, to value added chemicals can ease the burden on petroleum-based fine chemical synthesis. The active contribution of renewable energy sources along with low cost, environmental friendliness, and a simple reaction system must be adopted for better sustainability. In this context, photocatalytic selective hydrogenation of HMF to 2,5-bis(hydroxymethyl)furan (BHMF) was achieved over P25 titania nanoparticles without chemical squander. Simultaneously the photo-oxidation of p-methoxybenzyl alcohol (MeOBA) to p-methoxybenzaldehyde (MeOBaL), similar to biomass-derived vanillin, was carried out, abolishing the need of additional redox reagents. This system put forward the competent employment of photogenerated excitons for the valorization of lignocellulosic biomass to fine chemicals, which is an urgent requirement for sustainable chemical synthesis.