Transmittance predictions for transparent alumina ceramics based on the complete grain size distribution or a single mean grain size replacing the whole distribution

材料科学 粒度 透射率 陶瓷 粒度分布 分布(数学) 透明陶瓷 复合材料 矿物学 光电子学 粒径 数学 数学分析 化学工程 化学 工程类
作者
Soňa Hříbalová,Willi Pabst
出处
期刊:Journal of The European Ceramic Society [Elsevier BV]
卷期号:42 (12): 5093-5107 被引量:8
标识
DOI:10.1016/j.jeurceramsoc.2022.04.031
摘要

A simple method, based on the equivalent composite model or the dense polycrystalline model, is proposed for predicting the in-line transmittance in ceramics with a grain size distribution of birefringent crystallites. It is shown that the transmittance predictions based on the Rayleigh-Gans approximation are indistinguishable from those based on Mie theory, so that the latter can be replaced by the former. Based on normal distributions of different position and width it is shown that size distributions with smaller mean sizes lead to higher transmittance, whereas the effect of the distribution width on the transmittance is comparatively weak (with the narrowest distribution being the most favorable for high transmittance). The key result of this paper is the fact that for the distributions investigated (normal and log-normal) the transmittance prediction based the whole grain size distribution can be replaced by a transmittance prediction based on the geometric mean of the intensity-weighted distribution. • Transmittance is predicted for ceramics with birefringent crystallites (alumina). • Light scattering calculations take into account the whole grain size distribution. • Predictions based on the Rayleigh-Gans approximation can replace the Mie solution. • Size distributions with smaller mean sizes result in higher transmittance. • Transmittance prediction via geometric mean of intensity-weighted distribution.

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