Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine

Hydrazin? Kein Problem! Die Titelreaktion liefert erstmals Arylhydrazine durch Kreuzkupplung von Arylchloriden und -tosylaten mit Hydrazin (siehe Schema; Ad=Adamantyl, Ts=4-Toluolsulfonyl). Ein maßgeschneiderter Palladiumkatalysator sorgt dafür, dass der Prozess unter milden Bedingungen schnell und hoch chemoselektiv abläuft. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.