油页岩
多孔性
地质学
矿物学
构造盆地
打赌理论
地球化学
化学
地貌学
岩土工程
古生物学
吸附
有机化学
作者
Pengfei Zhang,Yajie Yin,Shuangfang Lu,Junqian Li,Xiangchun Chang,Junjian Zhang,Yumao Pang,Guo Chen,Yuqi Liu,Zhen Li
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2022-07-25
卷期号:36 (15): 8224-8237
被引量:15
标识
DOI:10.1021/acs.energyfuels.2c01763
摘要
The pore structure and its complexity and heterogeneity control the occurrence states and fluidity of shale oil. The multifractal theory effectively characterizes the complexity and heterogeneity of the shale pore structure. In this study, serial technologies were applied to detect the pore systems of shale obtained from Dongying Sag, Bohai Bay Basin in China. The multifractal characteristics of the pore structure of the shale were analyzed based on its nuclear magnetic resonance (NMR) T2 spectrum. The analysis results show that shale oil reservoirs can be classified into four types based on their T2 spectra. Type I shales T2 spectra show large p2 (1–20 ms), moderate p3 (>20 ms), but little p1 (<1 ms), characterized by large NMR and connected porosity, the lowest BET specific surface area (SSA), and the largest average pore throat diameter and S1 contents. Large p2, moderate p1, and tiny p3 are the main distinctions of type II shales with the largest NMR porosity, large connected porosity, and BET SSA. The T2 spectra of type III shales have large p1, moderate p2, and little p3, corresponding to large NMR porosity and BET SSA and the largest total organic content (TOC) and S1 contents but lower connected porosity. Type IV shales have the most significant contents of micropores with the relatively largest p1 in the T2 spectra characterized by the lowest NMR and connected porosity, the largest BET SSA, the lowest TOC, and S1 contents but the largest clay mineral contents. Both types III and IV shales are unfavorable shale oil reservoirs. Dq decreases monotonically as q increases, indicating the multifractal nature of shale pore structures. D0 varies from 0.88 to 1.00 (mean: 0.95), and Δα ranges from 1.24 to 2.82 (mean: 1.79), suggesting complex and heterogeneous pore structures. Types I and II shales have lower D0 values than types III and IV shales. Thus, type I organic-bearing massive felsic and type II organic-rich layered calcareous shales are favorable for shale oil reservoirs with large pores and large porosity. They have the least complex pore structures among the four shale types considered.
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