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Mo-doped Co3O4 ultrathin nanosheet arrays anchored on nickel foam as a bi-functional electrode for supercapacitor and overall water splitting

塔菲尔方程 超级电容器 材料科学 过电位 纳米片 分解水 化学工程 电极 电化学 电解 电解质 析氧 电容 纳米技术 比表面积 假电容器 兴奋剂 循环伏安法 冶金 化学 催化作用 物理化学 工程类 光催化 生物化学
作者
Shanshan Xiong,Shuting Weng,Yu Tang,Lei Qian,Yanqiu Xu,Xianfa Li,Hongjun Lin,Yanchao Xu,Yang Jiao,Jianrong Chen
出处
期刊:Journal of Colloid and Interface Science [Elsevier]
卷期号:602: 355-366 被引量:24
标识
DOI:10.1016/j.jcis.2021.06.019
摘要

Mo-doped Co 3 O 4 ultrathin nanosheets grown on nickel foam have been validated as an effective binder-free electrode material for electrocatalytic water splitting and supercapacitors. • Mo-doped Co 3 O 4 anchored on nickel foam were synthesized using a simple strategy. • Unique structure could provide active sites and shorten the ion diffusion distance. • The Mo-doped Co 3 O 4 shows superior performance for supercapacitor and water splitting. Simple preparation, favorable price and environmental protection have been a long-term challenge in the field of electrochemistry. Herein, we studied and prepared a bifunctional Mo-doped Co 3 O 4 ultrathin nanosheets, which has been validated as an effective binder-free electrode material for electrocatalytic water splitting and supercapacitors. The material has a large specific surface area, high electrical conductivity and exposure to more active sites, breaking down the limited performance and range of use of transition metal oxides. Benefiting from intriguing ultrathin property and conductivity, OER and HER process of 0.4Mo-Co 3 O 4 have a small Tafel slope of 83.7 and 98 mV dec −1 , respectively. The current density at 10 mA cm −2 show a low overpotential of 315 and 79 mV and significant stability. The water electrolytic device requires a potential of 1.64 V to reach 10 mA cm −2 , and the potential change is negligible after 12 h of continuous electrolysis. In addition, the manifest improved electrochemical performance of 0.3Mo-Co 3 O 4 as supercapacitor electrode material shows high areal capacitance 2815 mF cm −2 at 1 mA cm −2 , excellent rate performance (85% at 10 mA cm −2 ) and retains 90% of the initial capacitance by cycling 5000 at a current density of 10 mA cm −2 . Moreover, 0.3Mo-Co 3 O 4 ||0.3Mo-Co 3 O 4 symmetrical supercapacitor has a maximum volumetric energy density of 1.25 mW h cm −3 at a power density of 7.1 mW cm −3 and superior cycle life. The influence of doping on electrochemical performance was studied by changing the content of doped metal ions, which is of great significance for the exploration of supercapacitor and electrocatalytic hydrolysis of bifunctional electrode materials.
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