螺旋烯
绝对构型
化学
电子顺磁共振
光谱学
吸收光谱法
吸收(声学)
结晶学
圆二色性
自由基离子
立体化学
分子
材料科学
有机化学
离子
核磁共振
物理
光学
复合材料
量子力学
作者
Bettina D. Gliemann,Ana G. Petrovic,Eva M. Zolnhofer,Pavlo O. Dral,Frank Hampel,Georg Breitenbruch,Philipp Schulze,Vijay Raghavan,Karsten Meyer,Prasad L. Polavarapu,Nina Berova,Milan Kivala
标识
DOI:10.1002/asia.201601452
摘要
Abstract A stable chiral hetero[4]helicene radical cation was synthesized and characterized by UV/Vis absorption and EPR spectroscopy, as well as X‐ray crystallography. For the first time, a combination of chiroptical methods involving ECD, ORD, and VCD, supported by quantum mechanical predictions, enabled the elucidation of the absolute configuration of such open‐shell helical species.
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