Synthetic Control and Structural Stabilization of Ni-Rich Layered Oxides As High-Energy Cathode Materials for Lithium Ion Batteries

材料科学 退火(玻璃) 阴极 锂(药物) 电化学 氧化物 化学工程 相(物质) 化学 冶金 电极 物理化学 医学 工程类 内分泌学 有机化学
作者
Jianqing Zhao,Wenchang Zhu,Lijun Gao
出处
期刊:Meeting abstracts 卷期号:MA2018-01 (3): 361-361
标识
DOI:10.1149/ma2018-01/3/361
摘要

Ni-rich layered oxides (LiNi 1-x M x O 2 , M=Co, Mn, Al, etc., x<0.5) have been demonstrated as practical cathode materials for high-energy and high-power lithium ion batteries. However, various synthetic factors affect the layered structural ordering of LiNi 1-x M x O 2 and related electrochemical lithium storage performances. Herein, we report on developing a high-capacity Ni-rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 oxide with enhanced cycleability via the synthetic control. Systemic investigation is made to the phase evolution of LiNi 0.8 Co 0.1 Mn 0.1 O 2 oxide under different annealing temperatures by ex-situ and in-situ synchrotron X-ray diffraction (XRD) measurements, coupled with quantitative structural analysis through refinements. Structural characterization indicates an intriguing phase transition of LiNi 0.8 Co 0.1 Mn 0.1 O 2 from a rock-salt structure at low annealing temperatures directly to a layered α-NaFeO 2 -type structure with a R-3m space group at high temperatures. The in-situ XRD studies gain us access to the phase diagram in the confined Ni-rich region of the Ni-Mn-Co space, thereby enabling the design of synthetic protocols for preparing high-capacity LiNi 1-x-y Mn x Co y O 2 oxides with stabilized structure and reasonable cycling stability. Furthermore, a preheating process and Li 2 TiO 3 coating layer have been introduced during the synthesis of LiNi 0.8 Co 0.1 Mn 0.1 O 2 oxide, in order to manipulate the lithium source reaction by fabricating the outer shell in advance. As a result, the resulting LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode material reveals the higher degree of structural ordering and considerably enhanced lithium storage performances. This work offers a feasible route to optimize the layered structure of Ni-rich cathode materials via the synthetic control of the lithium source reaction, and further sheds light on the fundamental relationship between crystal structure and electrochemical performance for high-energy lithium ion batteries.

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