化学
部分
四硫富瓦烯
分子
立体化学
高分子化学
有机化学
作者
Zhe-Jun Lu,Jin-Po Wang,Qin‐Yu Zhu,Li-Bin Huo,Yu-Rong Qin,Jie Dai
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2010-01-01
卷期号:39 (11): 2798-2798
被引量:9
摘要
A new bifunctional tetrathiafulvalene (TTF) derivative has been designed and synthesized, in which the TTF moiety (a redox functional group) is integrated with a dioxotetraamine (a coordination functional group) structure. Like other dioxotetraamine compounds, it is capable of acting as an ion leaving and accepting ligand for protons and Cu(II) and Ni(II) ions in solution. Experiments of pH titration have shown that the TTF unit adds new redox properties to the traditional ligand. Oxidation of the ligand increases the acidity of the imido group and the coordination of metal ions is also sensitive to the oxidation state of the ligand. The ligand forms either a square coordinated Ni(II) complex with two deprotonated imido groups and two amino groups, or a pentacoordinated Cu(II) complex with an additional solvent molecule. The compounds form a belt structure with strong N–H⋯O hydrogen bonds, which is a basic character for this type of compound in the crystalline form.
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