催化作用
过电位
一氧化碳
化学
电解
无机化学
电化学
产量(工程)
碳纤维
二氧化碳
法拉第效率
有机化学
材料科学
电极
物理化学
冶金
复合材料
复合数
电解质
作者
Cyrille Costentin,Samuel Drouet,Marc Robert,J. M. SAVEANT
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2012-10-04
卷期号:338 (6103): 90-94
被引量:1137
标识
DOI:10.1126/science.1224581
摘要
Lending a Hand to CO 2 Reduction Although plants and microbes have been reducing CO 2 with ease for millennia, people still find it extremely challenging. A cost-effective synthetic scheme for transforming CO 2 into fuels and commodity chemicals would be a double boon, lowering atmospheric concentration of the greenhouse gas while supplementing (and perhaps ultimately replacing) dwindling petroleum feedstocks. Toward this end, Costentin et al. (p. 90 ) show that an iron catalyst for the electrochemical reduction of CO 2 to CO gets an efficiency boost from phenol substituents appended to the ligand framework.
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