卫星
激发
谱线
X射线光电子能谱
价(化学)
原子物理学
摇动
过渡金属
工作(物理)
核心电子
芯(光纤)
价电子
电子
化学
物理
核磁共振
光学
核物理学
量子力学
生物化学
天文
催化作用
作者
Marion A. Brisk,A. D. Baker
标识
DOI:10.1016/0368-2048(75)80061-2
摘要
Shake-up satellite peaks have been reported in the core electron spectra of various types of molecules. The specific valence excitation(s) giving rise to this extra structure has been assigned largely as a result of the application of the sudden approximation coupled with other considerations, e.g. transition energies. Satellite peaks appearing in the core electron spectra of first row transition metal complexes appear to be particularly interesting since existing data indicate that their positions and intensities convey information regarding some important properties of the complex. In this work reported shake-up satellite peaks are described and analyzed. In addition, some areas requiring more experimental work are pointed out, and a few potential applications of satellite peak data are mentioned.
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