光催化
共价键
三嗪
单体
材料科学
铂金
可见光谱
光化学
纳米技术
腈
催化作用
化学工程
高分子化学
聚合物
化学
有机化学
光电子学
复合材料
工程类
作者
Jinhong Bi,Wei Fang,Liuyi Li,Jin-Yun Wang,Shijing Liang,Yunhui He,Minghua Liu,Ling Wu
标识
DOI:10.1002/marc.201500270
摘要
Covalent triazine-based frameworks (CTFs) with a graphene-like layered morphology have been controllably synthesized by the trifluoromethanesulfonic acid-catalyzed nitrile trimerization reactions at room temperature via selecting different monomers. Platinum nanoparticles are well dispersed in CTF-T1, which is ascribed to the synergistic effects of the coordination of triazine moieties and the nanoscale confinement effect of CTFs. CTF-T1 exhibits excellent photocatalytic activity and stability for H2 evolution in the presence of platinum under visible light irradiation (λ ≥ 420 nm). The activity and stability of CTF-T1 are comparable to those of g-C3 N4 . Importantly, as a result of the tailorable electronic and spatial structures of CTFs that can be achieved through the judicial selection of monomers, CTFs not only show great potential as organic semiconductor for photocatalysis but also may provide a molecular-level understanding of the inherent heterogeneous photocatalysis.
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