适体
光电流
材料科学
表面等离子共振
检出限
纳米颗粒
电极
X射线光电子能谱
可见光谱
纳米载体
纳米技术
化学工程
异质结
光电子学
化学
色谱法
遗传学
生物
工程类
物理化学
作者
Yixuan Feng,Tao Yan,Tingting Wu,Ning Zhang,Qianqian Yang,Meng Sun,Liangguo Yan,Bin Du,Qin Wei
标识
DOI:10.1016/j.snb.2019.126817
摘要
A label-free photoelectrochemical (PEC) aptasensor for tetracycline (Tc) detection was successfully fabricated, and plasmon Au coupling with MOF-derived In2O3@g-C3N4 nanoarchitectures (AuInCN) with excellent PEC performance was employed as matrix for the first time. The homogeneous In2O3 nanoparticles (In2O3 NPs) derived from MIL-68(In) precursor were synthesized via calcination in air. The g-C3N4 nanosheets provided a favorable substrate for the fine distribution of In2O3 NPs. The In2O3@g-C3N4 (InCN) heterojunction with compact interface and matching band structure, facilitated the separation and transfer of electron-hole pairs. The surface plasmon resonance (SPR) of gold nanoparticles (Au NPs) could improve the light absorption and the photoelectron transfer of the modified electrode. Meanwhile, the decorated cysteamine stabilized Au NPs were also adequate to immobilize the SH-terminated aptamer as a biorecognition unit, and Tc molecules could be trapped through the specific interaction with the immobilized aptamer. An enhanced PEC photocurrent was realized under visible light illumination, due to the oxidation of captured Tc by photo-generated holes. Thereby, the concentration of Tc could be detected by observing the changes of photocurrent signals. Under optimized conditions, the PEC aptasensor exhibited the linear range from 0.01 nmol L−1 to 500 nmol L−1, with a detection limit (S/N = 3) of 3.3 pmol L−1. The prepared PEC aptasensor demonstrated acceptable stability, specificity and reproducibility, indicating the potential applications for the detection of Tc.
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