光催化
材料科学
拉曼光谱
可见光谱
吸收边
酮洛芬
光化学
带隙
金属有机骨架
吸收(声学)
辐照
纳米技术
催化作用
化学工程
核化学
光电子学
复合材料
光学
有机化学
化学
色谱法
吸附
工程类
物理
核物理学
作者
Guiliang Zhu,Sheng Feng,Shanshan Feng,Zhi‐Hui Zhang
标识
DOI:10.1016/j.matlet.2019.02.105
摘要
C-dots and metal organic frameworks (MOFs) have a wide range of applications in the field of photocatalysis. Here, C-dots/UiO-66-NH2 composites were successfully synthesized by a simple one-pot method. The synthesized samples were characterized by XRD, Raman, SEM, TEM, EDS, Mapping, UV-vis DRS, and PL spectra. Compared with UiO-66-NH2, the absorption edge of C-dots/UiO-66-NH2 extended from 439 nm to 534 nm. The experiments of photocatalytic degrading ketoprofen under visible-light irradiation (λ ≥ 420 nm) showed that C-dots/UiO-66-NH2 demonstrated stronger photocatalytic activity than UiO-66-NH2 for degrading ketoprofen (1.87 times that of UiO-66-NH2) and degraded 92% in 1 h. The improved photocatalytic activity was mostly caused by the reduced band gap and interfaces between UiO-66-NH2 and C-dots, absorbing more visible light and inhibiting electron-holes recombination.
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