Simulation on Critical Frequency of Polymer in Electrostrictive Properties

电致伸缩 材料科学 极化(电化学) 聚乙烯 放松(心理学) 低频 化学 复合材料 物理 压电 心理学 社会心理学 物理化学 天文
作者
Yulong Wang,Lei Zhu,Meng Wang,Lili Li,Junguo Gao,Ning Guo,Defeng Zang,Ji Liu
出处
期刊:Macromolecular Theory and Simulations [Wiley]
标识
DOI:10.1002/mats.202400045
摘要

Abstract The critical frequency and the relaxation time are analyzed through deformation and displacement during electrostriction which is induced by the electrical field at different frequencies. First, when the frequency is 50 Hz and the field strength is 2.5 kV mm −1 , the electrostrictive displacement of polyethylene is 6.72 × 10 −4 mm. After the data fitting, it is found that the displacement increases linearly with the square of field strength and that the proportional coefficient of 50 Hz is 1.08 × 10 −4 . Second, due to the influence of relaxation polarization and power loss, with the increase of frequency, the displacement and the proportional coefficient first increases then decreases, and when the frequency is 10 kHz, the displacement of 2.20 × 10 −6 mm and the proportional coefficient of 3.51 × 10 −7 have minimum values, which are 99.67% and 99.68% lower than that of 50 Hz, respectively. There is the critical frequency. Finally, based on the characteristic of anomalous dispersion, the relaxation time of polyethylene is 9.19 × 10 −6 s, which is in the time range of thermionic relaxation polarization and consistent with the actual situation. This analysis confirms the quantitative relationship between electrostrictive characteristics, field strength, and polarization. In addition, the relationship between frequency and strain is discussed, and the critical frequency in polymer and the relaxation time are confirmed.
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